When aliphatic amine and aromatic amine react with nitrous acid
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●Aromatic primary amines react with at 273–278 K to form aromatic diazonium salts.
●Aliphatic primary amines also react with at 273–278 K to form aliphatic diazonium salts. However, these are unstable even at low temperature and therefore, decompose readily to form alcohols (generally predominate) and is evolved.
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