Question

Which compound on nitration will give highest amount of
m-substituted product ?

Answer 1

Answer:

an aromatic compounds having electron withdrawing groups

Answer 2

The annilene will give mostly the meta nitro product.

Explanation:

• Annilene is a compound where there's an amine group on the benzene ring.

• This amine group in normal or basic conditions have a lone pair of electrons on the nitrogen.

• But in acidic condition, the lone pair of electron is donated to a proton which becomes the anilinium cation.

• The +R effect now fhanges ro - R efdect.

• This cation then tries ro withdraw electrons from benzene ring, which causes the coming nitro groups to get directed towards the meta position.

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