Which of the following are organometallic ?
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lithium, sodium, copper, zinc, magnesium....
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Answer:
Which of the following organometallic compound is σ and π bonded -
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Option (C) is correct.
[Co(CO)5 NH 3 ] +2 is σ and π bonded.
In this organometallic compound,bond between cobalt and CO ligands have both σ and π character.σ- bond formation between metal and carbon of CO takes place by overlap of filled bonding π 2p of CO with an empty metal d- orbital.
The 2nd overlap takes place between metal d- orbital with an empty antibonding pi orbital of the CO resulting in additional π- bond between the metal and same CO molecule.
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