Which of the following expressions correctly represents the
equivalent conductance at infinite dilution of Al₂(SO₄)₃,
Given that ∧° Al³⁺ L and ∧°SO₄²⁻ are the equivalent
conductances at infinite dilution of the respective ions?
(a) 1/3 ∧°Al³⁺ + 1/2 ∧°SO₄²⁻
(b) 2∧°Al³⁺ + 3∧°SO₄²⁻
(c) ∧°Al³⁺ + ∧°SO₄²⁻
(d) (∧°Al³⁺ + ∧°SO₄²⁻) × 6
Answers
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Option[A] is the answer.
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13
Expression that correctly represents the
equivalent conductance at infinite dilution of Al₂(SO₄)₃ is :
• Given : ∧° Al³⁺ L and ∧°SO₄²⁻ are the equivalent
conductances at infinite dilution of the respective ions
• Kohlrausch’s law states that the equivalent conductivity of an electrolyte at infinite dilution is equal to the sum of the conductances of the anions and cations. If a salt is dissolved in water, the conductivity of the solution is the sum of the conductances of the anions and cations.
• Hence, Answer is ∧°Al³⁺ + ∧°SO₄²⁻ (option c)
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