Which type of hydrocarbon can be nitrated in liquid phase?
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Answer:
Liquid phase nitration; In this method higher alkane is heated with fuming HNO3 at 413 K under pressure. (ii) Vapour phase nitration: Lower member of alkanes can be nitrated by vapour phase nitration i.e. by heating a gaseous mixture of hydrocarbon and nitric acid vapours at 673-773 K.
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Explanation:
(i) Liquid phase nitration; In this method higher alkane is heated with fuming HNO3 at 413 K under pressure. (ii) Vapour phase nitration: Lower member of alkanes can be nitrated by vapour phase nitration i.e. by heating a gaseous mixture of hydrocarbon and nitric acid vapours at 673-773 K.
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