wht is rosenmund rxn ???
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Answer:
Acyl halides when treated with Hydrogen in presence of Palladium dissolved in Barium Sulphate, ( Pd in BaSO4) with quinoline as solvent give reduced aldehydes as product.
This is known as Rosenmund reaction.
Equations
O O
||. ||
CH3-C-Cl --------> CH3-CH
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Explanation:
The Rosenmund reaction is a hydrogenation process where molecular hydrogen reacts with the acyl chloride in the presence of catalyst – palladium on barium sulfate. The barium sulfate reduces the activity of the palladium due to its low surface area, thereby preventing overreduction.
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