Why are carbonates and bicarbonates considered inorganic compounds?
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Cyanides, bicarbonates, carbonates, and some other carbon-containing compounds were classified as "inorganic" because of their source: they can be obtained in large quantity from minerals. ... By this definition, iron cyanide complexes, carbon dioxide, carbon tetrachloride, and sodium bicarbonate are all inorganic.
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i don't know actual reson
but it can be
that carbonate and bicarbonate doesn't dissolve naturally
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