why are group3b cations not precipitated in group2 , all precipitate being in the form of their sulphides?
Answers
Explanation:
Group 2: Acid-Insoluble Sulfides
Next, the acidic solution is saturated with H2S gas. Only those metal ions that form very insoluble sulfides, such as As3+, Bi3+, Cd2+, Cu2+, Hg2+, Sb3+, and Sn2+, precipitate as their sulfide salts under these acidic conditions. All others, such as Fe2+ and Zn2+, remain in solution. Once again, the precipitates are collected by filtration or centrifugation.
Group 3: Base-Insoluble Sulfides (and Hydroxides)
Ammonia or NaOH is now added to the solution until it is basic, and then (NH4)2S is added. This treatment removes any remaining cations that form insoluble hydroxides or sulfides. The divalent metal ions Co2+, Fe2+, Mn2+, Ni2+, and Zn2+ precipitate as their sulfides, and the trivalent metal ions Al3+ and Cr3+ precipitate as their hydroxides: Al(OH)3 and Cr(OH)3. If the mixture contains Fe3+, sulfide reduces the cation to Fe2+, which precipitates as FeS.