Question

Why boiling point of ether are lower than isomeric ether

Answer 1

The weak polarity of ethers do not appreciably affect their boiling points which are comparable to those of the alkenes of comparable molecular mass. Ethers have much lower boiling points as compared to isomeric alcohols. This is because alcohols molecules are associated by hydrogen bonds while ether molecules are not.

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Answer 2

Because hydrogen bonds can't form between the molecules in the ether, the boiling point of this compound is more than 80 C lower than the corresponding alcohol. ... As a result, ethers are less likely to be soluble in water than the alcohol with the same molecular weight.