Chemistry, asked by Ttarunmishraaaa7813, 1 year ago

Why chromate acts as oxidising agent only in acidic mediums?

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Answered by Anonymous
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In the dichromate ion, chromium is in the +6 oxidation state. If we assume the +3 oxidation is lower in energy (and more stable), then there will be a natural tendency for chromium to become reduced, and in turn oxidize something else. 

We can see this in the magnitude of the reduction potential: 
Cr2O7^2- + 14 H+ + 6 e- <==> 2 Cr3+ + 7 H2O .... E° = +1.33V☺️
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