Why do substances produced flame of different colours
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Heating an atom excites its electrons and they jump to higher energy levels. When the electrons return to lower energy levels, they emit energy in the form of light. The colour of the light depends on the difference in energy between the two levels.
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When you heat an atom, some of its electrons are "excited* to higher energy levels. When an electron drops from one level to a lower energy level, it emits a quantum of energy. ... The different mix of energy differences for each atom produces different colours. Each metal gives a characteristic flame emission spectrum.
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