why do the azonium salts of aromatic amines more stable when compared to aliphatic amines??
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it is because of dispersal of +ve charge on the benzene ring due to resonance.Aromatic diazonium salts are resonance stabilized and hence are more stable than the highly unstable aliphatic diazonium salts(which release N2 and ROH). However the aromatic diazonium salts are very stable for a short period of time.
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