Why do we take gaseous atom only for defining ionization enthalpy?
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Bcoz they are freely moveable in any state and ionisation enthalapy is directly proportional to size of atom and gases have a very small atoms so, this is the reason.
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it is because of this reasons the term isolated gaseous atom has been included in defining of ionization enthalpy and electron gain enthalpies of gaseous atoms must be determined is their respective ground states
i hope it's correct
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