Question

why does intramolecular hydrogen bonding not occur in picric acid?​

Answer 1

Answer:

intramolecular hydrogen bond in o- nitrophenol is sufficiently strong to withstand fission in dioxan and so hinder intermolecular hydrogen ...

Answer 2

Answer:

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Explanation:

The asymmetric unit of the title organic salt [systematic name: 1H-pyrazol-2-ium 2,4,6-tri­nitro­phenolate-1H-pyrazole (1/1)], H(C3H4N2)2+·C6H2N3O7-, consists of one picrate anion and one hydrogen-bonded dimer of a pyrazolium monocation. The H atom involved in the dimer N-H...N hydrogen bond is disordered over both symmetry-unique pyrazole mol­ecules with occupancies of 0.52 (5) and 0.48 (5). In the crystal, the component ions are linked into chains along [100] by two different bifurcated N-H...(O,O) hydrogen bonds. In addition, weak C-H...O hydrogen bonds link inversion-related chains, forming columns along [100].

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