Question

Why does sulphur shows paramagnetic behaviour in vapour state?

Answer 1

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In vapour state sulphur partly exists as S2 molecule and S2 molecule like O2 has two unpaired electrons in the anti bonding , orbital and hence exhibit paramagnetism. ... It donates its electron pair and forms a linkage with metal ion.

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Answer 2

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Sulphur in vapour state exhibits paramagnetism. In vapour state, sulphur partly exists as S2 molecule and has two unpaired electrons like O2 in the antibonding π-orbital. Hence, exhibits paramagnetism.

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