Chemistry, asked by maheentanwar5449, 11 months ago

Why is ortho nitrophenol steam volatile than p-nitrophenol

Answers

Answered by gauravarduino

1

Explanation:

o-Nitrophenol forms intramolecular H bond whereas molecules of p-Nitrophenol get associated through intermolecular H bond. During boiling, the strong intermolecular H bonding increases the boiling point but intramolecular H bonding cannot do so. Therefore, o-Nitrophenol is more steam volatile than p-Nitrophenol.

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