Why is trichloroacetic acid stronger than dichloroacetic acid?
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Dichloroacetic acid is a stronger acid than chloroacetic acid because the two chlorine atoms inductively withdraw more electron density from the O—H group than a single chlorine atom. The pKa of dichloroacetic acid is therefore smaller than the pKa of chloroacetic acid.
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Dichloriacetic acid is the stronger acid than trichloroacetic acid because two chlorine withdraw more electrons from O-H group than one chlorine
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