Why most metallic salts are insoluble in water?
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Insoluble salts are ionic compounds that are insoluble in water: the salt continues to exist as a solid rather than dissolving in the liquid. When a salt such as sodium chloride (table salt) dissolves in water, its ionic lattice is pulled apart so that the individual sodium and chloride ions go into solution.
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A polar solvent like water can form hydration spheres around the cations and anions of the metal salt. This reduces the ionic interactions making them similar to the water/water interactions and the salt/ water interactions. Non-polar organic solvents cannot do this. Hence metal salts do not dissolve in such solvents
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