Why NH3 is more basic than PH3 ?
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Phosphorus is big in size and phosphorus atom in PH3 has one lone pair of electron which is not available for donation hence PH3 is weaker then NH3..
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es nh3 is more basic than ph3 as nh3 has more density of electron.
owing it to the small sizeof nitrogen and p orbitals it has the ability to
form stronger bonds due to effective overlap .in ph3 however ,the large
size ofp result in the porbitals becomming diffusedpreventing effective overlap
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