Why nitrogen is gas and diatomic but phosphorus is solid?
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nitrogen is gas because it forms triple bond between two nitrogen molecules and phosphorus is solid because it forms bond between more than two phosphorus molecules
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In Nitrogen; small size 2p orbital. So, sideways overlap effectively and make Pπ-Pπ multiple bond. Hence Nitrogen is diatomic.
Whereas in Phosphorus; large sized 3p orbital doesn't effectively overlaps sideways and makes only sigma bond. Hence; Phosphorus is tetratomic.
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