why the lithium salts are found in hydrated state?
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As lithium has a high hydration enthalpy so it polarises with the water molecules easily and makes the salts hydrated unlike all other alkali metals which doesn't do so.
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Hence, Li+ ion can polarize water molecules more easily than other alkali metals. As a result, water molecules get attached to lithium salts as water of crystallization. Hence, lithium salts such as trihydrated lithium chloride (LiCl. 3H2O) are commonly hydrated.
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