why there is poor resonance in pethoxyphenol than phenol
Answers
Answer:
the oxygen bonded to the ring is more electronegative than carbon so it will increase acidity of the phenolic -OH group. In the p-position (4-methoxyphenol), only resonance will be at play and because it donates electron by resonance, this will decrease acidity
Explanation:
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why there is poor resonance in pethoxyphenol than phenol?
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o-Methoxy phenol is less acidic than phenol. ... In Phenol there are 4 resonating structure as it forms Phenoxide ion by losing its proton, but in o-methoxy phenol there is methyl group attached to the Oxygen, which is not a good leaving group and hence shows lesser resonating structures.
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- For the methoxy group,
- the oxygen bonded to the ring is more electronegative than carbon so it will increase acidity of the phenolic -OH group.
- In the p-position (4-methoxyphenol),
- only resonance will be at play and because it donates electron by resonance,
- this will decrease acidity.
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