Why vanadium hexacarbonyl is stable than chromium hexacarbonyl?
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Vanadium hexacarbonyl is the inorganic compound with the formula V(CO)6. ... V(CO)6 adopts an octahedral coordination geometry and is isostructural with chromium ...
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Explanation:
The fact that the stable mononuclear vanadium carbonyl V(CO)6 fails to satisfy the 18-electron rule has led to an investigation of the binuclear vanadium carbonyls V2(CO)n (n = 10-12) using methods from density functional theory.
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