write koble's reaction
Answers
) Kolbe's reaction: When phenol is treated with sodium hydroxide, sodium phenoxide is produced. This sodium phenoxide when treated with carbon dioxide, followed by acidification, undergoes electrophilic substitution to give ortho-hydroxybenzoic acid as the main product. This reaction is known as Kolbe's reaction.
Answer:
When phenol is treated with sodium hydroxide, phenoxide ion is generated. The phenoxide ion generated is more reactive than phenol towards electrophilic aromatic substitution reaction. Hence it undergoes electrophilic substitution reaction with carbon dioxide which is a weak electrophile. Ortho-hydroxybenzoic acid (salicylic acid) is formed as the major product. This reaction is popularly known as Kolbe’s reaction. It is named after the scientist Hermann Kolbe.
Explanation: