Write the chemical properties of hydrogen with following
i. Nitrogen
ii. Metallic Oxide
iii. Molten Sulphur
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Nitrogen:
- The seventh element of the periodic table between carbon and oxygen is Nitrogen.
- It’s an important part of amino acids.
- Around eighty percent of the Earth’s atmosphere comprises nitrogen gas.
- It has no colour, mostly diatomic non metal gas along with odourless and colourless in nature.
- Since it has five electrons in its outer shell, most of its compounds are trivalent.
- It is a constituent of all living tissues. Since it is a component of DNA and part of a genetic code, it is an essential element of life.
- It is found in nitrates and nitrites in soil and water.
Metallic Oxide:
- Metal oxides are crystalline solids that contain a metal cation and an oxide anion.
- They typically react with water to form bases or with acids to form salts.
- The alkali metals and alkaline earth metals form three different types of binary oxygen compounds:
1. Oxides, containing oxide ions, O²-,
2. Peroxides, containing peroxide ions, O²²−, which contain oxygen-oxygen covalent single bonds, and
3. Superoxides, containing superoxide ions, O²−, which also have oxygen-oxygen covalent bonds but with one fewer negative charge than peroxide ions.
Alkali metals (which have a +1 oxidation state) form oxides, M²O, peroxides, M²O², and superoxides, MO². (M represents a metal atom.)
- The alkaline earth metals (with a +2 oxidation state) form only oxides, MO, and peroxides, MO².
- All the alkali metal oxides can be prepared by heating the corresponding metal nitrate with the elemental metal.
2MNO³ + 10M + heat → 6M²O + N2
- A general preparation of the alkaline earth oxides involves heating the metal carbonates.
Molten Sulphur:
- Sulfur burns with a blue flame, concomitant with formation of sulfur dioxide, notable for its peculiar suffocating odor.
- Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene.
- The first and the second ionization energies of sulfur are 999.6 and 2252 kJ/mol, respectively.
- Despite such figures, S2+ is rare, with S+4 and S6+ being more common.
- The fourth and sixth ionization energies are 4556 and 8495.8 kJ/mol.
- The magnitude of the figures is caused by electron transfer between orbitals; these states are only stable with strong oxidants such as fluorine, oxygen, and chlorine.
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