Question

Write the mechanism of Carbyl amine reaction.

Answer 1

Explanation:

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Answer 2

Answer :-

The carbylamines reaction, also known as Hofmann's isocyanide test is a chemical test for the detection of primary amines. In this reaction, the analyte is heated with alcoholic potassium hydroxide and chloroform. If a primary amine is present, the isocyanide (carbylamines) is formed which are foul smelling substances.

Mechanism :-

• The first step is the dehydrohalogenation (hydrogen halide removal from a given substrate) of chloroform to produce dichlorocarbene intermediate, which is very reactive.
• The electrophilic dichlorocarbene attacks the primary amine's nucleophilic nitrogen.
• The elimination of hydrochloric acid leads to an isonitrile formation.

For reaction, refer attachment.

Remarks :-

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