10 moles of pure PCl5 gas is put into a closed container of volume 'V' and temperature 'T' and allowed to reach equilibrium, at an equilibrium pressure 20 atm. The pure PCl5 is found to be 50% dissociated at equilibrium. PCl5(g)⇔PCl3(g)+Cl2(g) The partial pressure of PCl5, if an equilibrium is established at new equilibrium pressure 35 atm by changing volume is :
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