A 100W,200V incandescent lamp is connected in series with an electrolytic cell containing copper sulphate solution.What weight of copper will be deposited by a current flowing for 5 hours?(at. Wt. of Cu=63.54)
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Current,I=
Volt
Watt
=
110 V
200 W
=1.818 A
The quantity of electricity passed =Q(C)=1.818 A×30×60 s=3272.72 C
Atomic weight of zinc = 65.4 gm/mol
Moles of electrons passed =
96500
mol e
−
C
Q(C)
=
96500
mol e
−
C
3272.72 C
=0.0339 mol e
−
The weight of zinc deposited =molar mass of Zn×moleratio ×moles of electrons passed
=65.4
mol
g
×
2 mol e
−
1 mol Zn
× 0.0339 mol e
−
=1.1 gm
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