Chemistry, asked by harshabalijireddy, 10 months ago

An optically active aldotetrose which retains its optical activity with aqueous Br2 but loses it with conc. HNO3 has the following structure:

Answers

Answered by topwriters
1

Glyceraldehydes B and D lose their optical activity when oxidized by HNO3

Explanation:

The question is incomplete. Please refer to the attached picture for the options for the given question.

Studying the given elements, we find that the elements B and D will lose their optical activity when they react with HNO3, but not with aqueous Br2. B and D are glyceraldehydes. Br2 oxidizes -CHO group to  -COOH group with HNO3 causing the element to lose its optical activity.

With A and C, there is symmetry and hence they are not oxidized. So they retain their optical activity.

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