Question

An organic compound a c6 h6 gives characteristics reaction with unutilized if pcl3 solution on treatment with seo2 and n a o h at 400 kelvin under pressure gives b which on acidification gives compound c c reacts with acid chloride and gives day which is a painkiller deduce the structure and iupac names of a b c and d

Answer 1

A is phenol, B is sodium salicylate, C is salicylic acid and D is aspirin.

Explanation:

• The compound A is phenol because its said that the compound can form colour with neutral FeCl3 solution.

• The complex formed with iron is hexa phenolic complex which has a characteristics colour.

• Fe3+ + 6 Ph-Oh = Fe(PhOH)6 3+

• This compound when treated with carbon dioxide and NaOH, gives the sodium salicylate.

• Ph - OH + CO2 = Ph-OH- COONa.

• This salt when treated with acid forms the salicylic acid.

• This acid when treated with Acetyl chloride forms the hydrochloric acid and aspirin or acetyl salicylate.

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Answer 2

Answer:

Two moles of organic compound a on treatment with a strong base gives two compounds b and c. Compound b on dehydrogenation with cu gives a while acidification of c yields carboxylic acid d with molecular formula of ch2o2. Identify the compounds a, b, c and d. Write all chemical reactions involved.