Benzoic acid decarboxylation which acid decarboxylate easily
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Beta-keto carboxylic acids (like Acetoacetic acid) and dicarboxylic acids tend to decompose directly on heating.
This is because:
1.Stabilized carbanion formation (if the carboxylate as opposed to the acid decarboxylates)
2. H- bonding makes it easy to transfer acidic H into the ketone oxygen, and eliminate CO2, forming an enol that tautomerizes.
This is because:
1.Stabilized carbanion formation (if the carboxylate as opposed to the acid decarboxylates)
2. H- bonding makes it easy to transfer acidic H into the ketone oxygen, and eliminate CO2, forming an enol that tautomerizes.
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Explanation:
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