By using concept of exchange energy which is more stable.
3d6 3d5 3d4
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Second electronic configuration is more stable than the first one. This is because it is half filled and thus symmetrical.
When orbitals are half-filled or fully filled, then the electronic configuration becomes more stable.
Accordning half-filled electronic configuration.
3d54s1 is more stable then 3d44s2.
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