for equilibrium AB =A+B at given temperature, the pressure at which one-third of AB is dissociated is numerically equal to
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Given :
AB (g) ⇔ A(g) + B(g)
To find :
Pressure at which one third of AB is dissociated
Solution :
- AB (g) ⇔ A(g) + B(g)
t =0 a 0 0
t = t₁ a-x x x
- Kp = (Pa × Pb) / Pab
= [xP/(a+x)]² / [(a-x)P/(a+x)]
= x²P / (a²-x²) [x/a = 1/3]
P = 8Kp
The pressure at one third of dissociation is 8Kp
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