For the following reaction
CCl4 (l) + H2 (g) → HCl (g) + CHCl3 (l)ΔrG° = – 103.7 kJ mol–1 at 298 K. Calculate the equilibrium constant for
this reaction
Answers
Answer:
The equilibrium constant for the reaction CCl₄ (l) + H₂ (g) → HCl (g) + CHCl₃ (l) is 1506577960458601000.
Given:
The value of ΔrG° = – 103.7 kJ mol–1 at
Temperature of 298 K.
To find:
The equilibrium constant for the reaction CCl₄ (l) + H₂ (g) → HCl (g) + CHCl₃ (l) at 298 K
Solution:
The equilibrium constant for the reaction at 298 K can be calculated using the following equation:
K = e^(-ΔrG°/RT )
Where R is the universal gas constant (8.314 J/molK) and T is the temperature in Kelvin (298 K).
Plugging in the values, we get:
K = e^(-(-103.7 kJ/mol))/(0.008314 kJ/molK * 298 K)
K = e^(103.7/2.4472)
K = e^(41.85549)
K = 1506577960458601000
This can be interpreted as the ratio of the products to the reactants at equilibrium, which is 1506577960458601000 times higher than the starting concentration of reactants.
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