Give reasons for the following:
(a) Red phoshorus is less reactive than white phosphorus.
(b) Electron gain enthalpies of halogens are largely negative
(c) N₂O₅ is more acidic than N₂O₃.
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a) White phosphorus is made up of discrete P4 tetrahedra which are subjected to very high angular strain as the angles is 60 degrees.
Red phosphorus is a polymer of P4 tetrahedra, which has much less angular strain.
This high angular strain makes white phosphorus unstable and highly reactive.
Red phosphorus is a polymer of P4 tetrahedra, which has much less angular strain.
This high angular strain makes white phosphorus unstable and highly reactive.
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