H. A substance, on analysis, gave
the following percent composition:
Na = 43.4 %, C = 11.3 % and
0 = 45.3 %. Calculate the empirical
formula. (At. mass Na = 23 u, C = 12
u, 0= 16 u).
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Explanation :
Na = 43.4%
C = 11.3
O = 43.3%
relative number of moles
of Na = 43.4/23 = 1.88
of C = 11.3/12 = 0.94
of O = 43.3/16 = 2.71
simple ratio of moles
of Na = 1.88/0.94 = 2
of C = 0.94/0.94 = 1
of O = 2.71/0.94 = 2.87 ~ 3
empirical formula = Na2CO3
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