in fractional distillation process ethanol boil at
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room temperature
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Ethanol boils at 78.4 °C (173.1 °F) while water boils at 100 °C (212 °F). So, by heating the mixture, the most volatile component (ethanol) will concentrate to a greater degree in the vapor leaving the liquid. Some mixtures form azeotropes, where the mixture boils at a lower temperature than either component.
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