Metals are expand on heating while contract on cooling. Both are
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expand when they are heated and contract when they are cooled. Increased temperature increases the frequency and magnitude of the molecular motion of the material and produces more energetic collisions. Increasing the energy of the collisions forces the molecules further apart and causes the material to expand.
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When a material is heated, the kinetic energy of that material increases and its atoms and molecules move about more. This means that each atom will take up more space due to its movement so the material will expand. ... Some metals expand more than others due to differences in the forces between the atoms / molecules.
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