The half life for N2O5 decomposition reaction is 2.4hours at STP. Starting with 10.8 grams of N2O5, how much oxygen will be obtained after a period of 9.6 hours?
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- Oxygen that will be obtained after a period of 9.6 hours is 0.07 liter.
Given-
- Half life of N₂O₅ = 2.4 hours
- Initial mass of N₂O₅ = 10.8 grams
- Moles of N₂O₅ = 10.8/108 = 0.1 moles
Decomposition reaction of N₂O₅ is-
N₂O₅ → 2 NO₂ + 1/2 O₂
Half life of N₂O₅ = 2.4 hours
T 1/2 = ln 2 / k = 2.4 hours
⇒ k = ln2 / 2.4
Now, at T = 9.6 hours
k = ln (0.1/N)/9.6 = ln 2 / 9.6
By solving the above equation we get N = 0.1 / 16
Now number of liter of O₂ = N × 22.4 / 2 = 0.07 Liter.
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