Chemistry, asked by prem8782, 9 months ago

the value of CFSE for d3 metal ion configuration is (a) -0. 8 b-1. 2 c- -1. 2 d- -0. 6 bhai jladi btaao​

Answers

Answered by nirman95
0

Value of CFSE for d3 in octahedral complexes is

  • \boxed{\sf{-1.2 \Delta_{0}}}

CFSE is the acronym for Crystal Field Stabilization Energy , helps to calculate the stabilisation energies for various octahedral complexes.

Calculation:

Arrangement of Electrons in the split "d" orbitals in the octahedral complexes ;

0 \Delta_{0} \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \: \:  \:  \:  \boxed{ \underline{ - }} \:  \:  \:  \boxed{\underline{  - }}  \:  \:  \:  \:   \:  \:   e_{g} \\  \\  3 \times (  - \frac{ 2}{5}) \Delta_{0}  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \:  \: \boxed{\underline{ \red{ \uparrow}}} \:  \: \boxed{\underline{ \red{ \uparrow}}} \:  \: \boxed{\underline{  \red{\uparrow}}}  \:  \:  \:  \:  t_{2}g

\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}\underline{-}

 \sf{ \therefore \: CFSE = 3 \times (  - \dfrac{2}{5} )\Delta_{0} }

 \sf{  =  > \: CFSE =  - \dfrac{6}{5} \Delta_{0} }

 \sf{  =  > \: CFSE =  - 1.2\Delta_{0} }

So, final answer is:

 \boxed{ \large{ \sf{ \red{  \: CFSE =  - 1.2\Delta_{0} }}}}

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