Two moles of an ideal gas initially at 27°c
and one atmospheric pressure are
compressed isothermally and reversibly
till the final pressure of the gas is 10 atm.
Calculate q, W and ∆u for the process.
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Explanation:
Given,
T=(27+273)K=300K
∆T=0 ( As temperature is constant)
P1=1atm
P2=10atm
n=2 moles
As per question,
Work=2.303×2×8.314×300×log(10/1)
= 11488 J
Now,
∆U= 2×c×0= 0
Now, from 1st law of thermodynamics
∆U=q+W
0=q+W
q= -W
q= -11488 J
Formulas used,
W=2.303 nRT log(P2/P1)
∆U=q+W
∆U= nC∆T
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