What is interfering radicals in salt analysis
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What are the interfering radicals? How do they interfere in systematic separation of cationic radicals? Why is it necessary to remove them before IIIrd gr analysis? Why don't they interfere in Ist or IInd group analysis? Interfering radicals are oxalate, tartrate, fluoride, borate and phosphate and they are anionic radicals. They form complex with IIIrd gr group reagent ammonium chloride and ammonium hydroxide. This leads to incomplete precipitation of IIIrd group cations and causes immature precipitation of IVth and Vth group cations in alkaline medium. Let’s try to understand it.
Oxalate, tartrate, fluoride, borate, silicate and phosphate of the metals are soluble in acidic medium.
Oxalate, tartrate, fluoride, borate, silicate and phosphate of the metals are soluble in acidic medium.
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