What is meant by chelate effect? Give an example
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[texWhen a ligand attaches to the metal ion in a manner that forms a ring, then the metal- ligand association is found to be more stable. In other words, we can say that complexes containing chelate rings are more stable than complexes without rings. This is known as the chelate effect.]\huge\mathfrak{\orange{♠♠♠♠♠♠♠♠♠♠}}[/tex]
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The chelate effect is the enhanced affinity of chelating ligands for a metal ion compared to the affinity of a collection of similar nonchelating (monodentate) ligands for the same metal.
EXAMPLE
Comparison of the binding of 2,2'-bipyridine with pyridine or 1,2-diaminoethane (ethylenediamine=en) with ammonia.
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