When deltaH is nearly equal to delta U
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Explanation:
When deltaH is negative it implies the reaction is exothermic in nature evolving heat where as positive deltaH represents the endothermic reaction involving absorption of heat from the surroundings.
∆H=-ve then it is exothermic
∆H=+ve then it is endothermic
At constant volume ∆v=0
∆U=ab
When no work is done ∆H=∆U=qv
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