When electromagnetic radiation of wavelength 300nm falls on the surface of sodium, electrons are emitted with a kinetic energy of 1.68*10^5 J mol^-1.What is the minimum energy to remove an electron from sodium? What is the maximum wavelength that will cause a photoeclectron to be emitted?
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8
Answer:
Given:
wavelength =300nm=300x 10⁻⁹m
h=planks constant=6.62 x 10⁻³⁴Js
c=velocity of light =3x10⁸ m/s
E=hv=hc/λ
⇒(6.62 x 10⁻³⁴ x3x10⁸)/300x 10⁻⁹
=6.62 x 10⁻⁹J
so, Kinetic energy for for 1 mole of photons=6.62 x 10⁻⁹ x6.022 x 10²³
=3.99x 10⁵J
so ,minimum amount of energy required to remove 1 mole of electrons from sodium atoms is
=(3.99 x 10 ⁵)- (1.68 x 10⁵)
=2.31 x 10 ⁵J
∴ minimum energy required to remove 1 electron from Na atom=
⇒2.31 x 10⁵/6.022 x 10²³
⇒3.84 x 10⁻¹⁹ J
Now maximum wavelelngth = λ=hc/E=(6.62 x 10⁻³⁴ x 3 x 10⁸)/3.84x 10 ⁻¹⁹
=5.17 x 10⁻⁷m=517nm
Hope it helps
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