Which of the following best doseribe
, the, relation
between
isothermal Compressibility(Kt) and adiabatic compressibility (Ks)is?
Answers
Explanation:
Compressibility β is defined as the reciprocal of bulk modulus (k) and is equal to the ratio of the fractional change in volume to the stress (pressure) applied on the body.
β=1k=−1V∂V∂p … … … (1)
Since the question is about isothermal and adiabatic compressibility, take the example of ideal gas.
We have equation for isothermal process (for one mole of gas for simplicity)
pV= constant
We differentiate this to get
p∂V+V∂p=0
⇒−1V∂V∂p=1p
The left hand side of this expression is isothermal compressibility (see equation (1)). Thus
βiso=1p … … … (2)
Now we have the equation for adiabetic process
pVγ = constant
We differentiate this to have
pγVγ−1+Vγ∂p∂V=0
A little rearrangement yields
−1V∂V∂p =1γp
⇒βadia=1γp … … … (3)
Since γ is always greater than 1, therefore from equations (2) and (3) it is clear that
βiso>βadia