Which one of the following reactions is expected
to readily give a hydrocarbon product in good
yields ?
Electrolytic
(a) RCOOK ⟶
oxidation
Br₂
(b) RCOO⁻Ag⁺ ⟶
Cl₂
(c) CH₃CH₃ ⟶
hບ
C₂H₅OH
(d) (CH₃)₃ CCI ⟶
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(a) RCOOK ----electrolytic ---oxidation----->
Explanation:
When an aqueous solution of sodium or potassium salt of carboxylic acid is electrolysed, hydrocarbon is evolved at the anode.
2RCOOK ----electrolytic ---oxidation-----> 2RCOO- (anode) + 2K+ (cathode)
At anode: 2RCOO- - 2e- -----> R-R (Alkne) + 2CO2
Option A is the answer.
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