Which reagent will you use for the following reaction?
CH₃CH₂CH₂CH₃ → CH₃CH₂CH₂CH₂Cl + CH₃CH₂CHClCH₃
(a) Cl₂ /UV light
(b) NaCl + H₂SO₄
(c) Cl₂ gas in dark
(d) Cl₂ gas in the presence of iron in dark
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Answer:
(a) CL2 / UV light is the right answer
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Reagent we would use is :
• Cl₂ /UV light for given below reaction
• CH₃CH₂CH₂CH₃ → CH₃CH₂CH₂CH₂Cl + CH₃CH₂CHClCH₃
• Chlorination under the presence of UV light gives free radical substitution mono-chlorinated isomeric products.
• When butane reacts with chlorine in presence of sunlight, it gets chlorinated at the "1" position to give 1-chlorobutane or at "2' position to give 2-chlorobutane
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