Question

Why do primary amine have higher boiling poing than ter?

Answer 1

Answer: Boiling point depends upon intermolecular forces of attraction i.e. the attractive forces existing between the molecules of liquid under considerations. H-bonding plays a significant role in determining the intermolecular forces. ... so the boiling point of primary amines > tertiary amines.

Answer 2

hey here is your answer

Boiling point of amines have high boiling point due to presence of hydrogen bonding between amine molecules. But the boiling point decreases with increase in alkyl groups attached to the N atom, because the number of H atoms present for hydrogen bonding decreases.

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