Why inductive effect operate only on sigma bond not on py bond ??
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If I'm not mistaken a good example of the inductive effect through multiple bonds is trifluoro-acetic-acid, or F3CCOOHFX3CCOOH. The proton is so electron deficient that it is easily abstracted by anything that can act as a base. The not 'fluorinated' equivalent, acetic acid, is not nearly as strong an acid.
The reason for the difference in acidity, is the difference in electro negativity between hydrogen atoms and fluorine. Due to the very large electro-negativity of fluorine atoms the electrons in the acid protons are 'pulled' towards it, leading to a clear example of the inductive effect over multiple bonds.
A comment on one of the comments below the question: Electron displacement does occur in double bonds. A good example is the carbonyl functional group (C=O) in a molecule. The inductive effect results in a slightly more positive charge on the Carbon atom and slightly higher at the O-atom. This is also due to electro-negativity and results in the reactivity of the C=O functional group.
Hope this helped!
The reason for the difference in acidity, is the difference in electro negativity between hydrogen atoms and fluorine. Due to the very large electro-negativity of fluorine atoms the electrons in the acid protons are 'pulled' towards it, leading to a clear example of the inductive effect over multiple bonds.
A comment on one of the comments below the question: Electron displacement does occur in double bonds. A good example is the carbonyl functional group (C=O) in a molecule. The inductive effect results in a slightly more positive charge on the Carbon atom and slightly higher at the O-atom. This is also due to electro-negativity and results in the reactivity of the C=O functional group.
Hope this helped!
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